National Geographic Today
As far back as the 1880s, miners in North Canada, South Africa, and Scandinavia have reported mysterious, foul smelling gases that hiss and spit from crevices deep in mineshafts. Now scientists have discovered the origin of these gases and have found that these anomalous emissions may provide a missing link in the evolution of life on Earth.
"Everyone thought the presence of these gases was really weird, because they didn't fit with the geology of the area," said geochemist Barbara Sherwood Lollar, of the University of Toronto in Canada, who led the study that first analyzed these gases.
The gases that Sherwood Lollar's team found—natural hydrocarbons like methane, ethane, propane, and butane, all of which are fossil fuels—are usually formed from processes associated with life. Bacteria in swamps, for example, produce methane, and natural gas is produced from decomposed plants and animals, like dinosaurs that lived millions of years ago. But these particular gases seemed to have no links to life.
Sherwood Lollar's team descended into mineshafts, some up to four kilometers (three miles) deep, and found that the gas was escaping from rocks formed during the Precambrian period—about 4 billion years ago, before life began.
"Barbara [Sherwood Lollar] has found that these gases have a chemical rather than biological origin. And that is very interesting and very significant," said microbial geochemist Philip Bennett, of the University of Texas at Austin.
There has been continuing debate over how hydrocarbons, which are some of the simpler building blocks of life, may have arisen. It is generally accepted that on the early Earth there was carbon dioxide, methane, water and hydrogen. But how these compounds formed simple molecules like ethane, propane and butane has not been shown.
Gases Are Produced Inorganically
Lollar is the first to locate a place on Earth that spews these ancient gases, and to prove that these compounds are being inorganically produced, said Keith Kvenvolden, a senior scientist at the U.S. Geological Survey in Menlo Park, California. Although people had noticed small methane emissions along ocean ridges and suspected the gas has chemical origins, no one had found such a site on land, he added.
"She has really proven it. She observed hydrocarbons in a place where they shouldn't be and used new state-of-the-art methods to prove the gases did not come from [life] processes," said Bennet.
After collecting the gases from these mines, Sherwood Lollar analyzed the very atoms that make up these gases using a new technique called "Continuous Flow Stable Isotope Mass Spectrometry."
Hydrocarbons produced from living organisms are rich in the light forms, or isotopes, of hydrogen and carbon. By contrast, when these same types of hydrocarbons are produced in the laboratory, or in space on meteorites, they are richer in the heavier hydrogen and carbon isotopes.
The chemical signature of the gases from North Canadian mines matched the chemical signatures of hydrocarbons like those from the Murchison meteorite and laboratory produced gases.
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